extraction and determination of molybdenum

The extraction and determination of molybdenum as the ...

A method is presented for the determination of molybdenum by extraction of its thiocyanate complex with methyl isobutyl ketone. The method is accurate to ±4% or 3 μg of molybdenum, whichever is greater. The only elements which cause interference are rhenium (serious), platinum, palladium, rhodium, selenium and tellurium. The method has been applied to a number of standard samples with ...

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Extraction and determination of molybdenum with tributyl ...

A differential spectrophotometric method is described for the determination of molybdenum by means of solvent extraction with tributylphosphate of the peroxymolybdate complex formed with H 2 O 2 in 3.5N H 2 SO 4. The extraction parameters are studied, and the behaviour of some other ions is reported. The method is used for ore analysis.

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Extraction and spectrophotometric determination of ...

01/04/1987  Extraction and spectrophotometric determination of molybdenum(VI) ... Determination of molybdenum in steel samples The proposed method was applied to the deter- mination of molybdenum in carbon steels (NBS 362, JSS 169-3 and 171-3). As the presence of certain ions leads to less satisfactory results, we examined mask- ing of these ions. Addition of masking agents de-

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SPECTROPHOTOMETRIC DETERMINATION OF

Molybdenum determination, Solvent extraction, Spectrophotometry, 2,6-dithiol-4-methylphenol, Environmental analysis. INTRODUCTION: Molybdenum is the one utmost important element for many organisms and has a wide distribution throughout nature 1. Molybdenum is a bio-essential element and its occurrence in water samples is of interest from both environmental and chemical points of view 2 ...

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Extraction and Spectrophotometric Determination of ...

01/04/2019  Abstract. An extraction-spectrophotometric method has been developed for the determination of trace molybdenum(VI) using a newly synthesized benzopyran derivative, 3-hydroxy-2-[3-(4-methoxyphenyl)-1-phenyl-4-pyrazolyl]-4-oxo-4H-1-benzopyran (HMPPB).The method involves formation of a 1 : 2 (M : L) yellow complex between Mo(VI) and HMPPB from 0.02–0.06 M H 2 SO 4

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(PDF) Determination of molybdenum in extracts of soil and ...

Determination of molybdenum in extracts of soil and sewage sludge CRMs after fractionation by means of BCR modified sequential extraction procedure July 2010 Talanta 82(2):582-6

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Trace level determination of molybdenum in environmental ...

15/01/2009  A 15 × 10 −3 M solution of N-phenybenzimidoyl thiourea in 1-pentanol was used for the extraction of the molybdenum complex that was synthesized by condensation of N-phenylbenzimidoyl chloride with thiourea in equimolar ratio as described in literature . 2.3. Sample collection and preparation for the determination of molybdenum

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Spectrophotometric determination of molybdenum using ...

Abstract: A new spectrophotometric method has been developed for determination of molybdenum using surfactant-mediated liquid{liquid extraction. Molybdenum(V) obtained by ascorbic acid reduction in 2.5 M H2 SO4 reacted spontaneously with thiocyanate and cetyl trimethyl ammonium bromide (CTAB), forming an intense orange yellow

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A colorimetric method for the determination of

Molybdenum is then separated from iron by extraction as the thiocyanate, which is then decomposed by digestion with sulphuric acid. The molybdenum is finally precipitated as the dithiol complex and extracted by amyl acetate for colorimetric estimation. The whole determination can be carried out in a Quickfit test‐tube and is both rapid and accurate.

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Extractive Spectrophotometric Method for Determination

This forms the basis of the proposed extractive spectrophotometric method for determination of molybdenum after its extraction in the form of Mo(V)-CHHB complex. The method has been successfully applied to the analysis of a large variety of samples with diverse matrices such as steels, reverberatory flue dusts, different types of water samples including industrial effluents, and a wide

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(PDF) Extraction and Spectrophotometric

Preceded by a solvent extraction of Mo (VI) oxinate in chloroform, the DP method was used for the determination of molybdenum. In the presence of 0.2 M tri-BAP as supporting electrolyte, the ...

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Extraction and Spectrophotometric Determination of ...

Extraction and Spectrophotometric Determination of Molybdenum and Tungsten with 2-Thenoyltrifluoroacetone. Application to Alloy Steels. Application to Alloy Steels. A. K. De

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Extraction and Spectrophotometric Determination of ...

A sensitive spectrophotometric method is developed for the determination of small amounts of molybdenum based on the extraction of molybdenum-thiocyanate-4-acetyl-2-(acetylamino)-5-dimethyl- 2-1,3 ...

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Extraction and Spectrophotometric Determination of ...

Abstract. An extraction-spectrophotometric method has been developed for the determination of trace molybdenum(VI) using a newly synthesized benzopyran derivative, 3-hydroxy-2-[3-(4-methoxyphenyl)-1-phenyl-4-pyrazolyl]-4-oxo-4H-1-benzopyran (HMPPB).The method involves formation of a 1 : 2 (M : L) yellow complex between Mo(VI) and HMPPB from 0.02–0.06 M H 2 SO 4 medium.

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(PDF) Determination of molybdenum in extracts of soil

Determination of molybdenum in extracts of soil and sewage sludge CRMs after fractionation by means of BCR modified sequential extraction procedure July 2010 Talanta 82(2):582-6

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Extractive Spectrophotometric Method for

This forms the basis of the proposed extractive spectrophotometric method for determination of molybdenum after its extraction in the form of Mo(V)-CHHB complex. The method has been successfully applied to the analysis of a large variety of samples with diverse matrices such as steels, reverberatory flue dusts, different types of water samples including industrial effluents, and a wide

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Spectrophotometric determination of molybdenum using ...

Abstract: A new spectrophotometric method has been developed for determination of molybdenum using surfactant-mediated liquid{liquid extraction. Molybdenum(V) obtained by ascorbic acid reduction in 2.5 M H2 SO4 reacted spontaneously with thiocyanate and cetyl trimethyl ammonium bromide (CTAB), forming an intense orange yellow

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Cloud-point extraction of molybdenum in plants and ...

Molybdenum in plant digests was accurately determined by cloud point extraction and quantification by isotope dilution inductively coupled plasma mass spectrometry.Plant digests spiked with 98 Mo received 8-hydroxyquinoline and the surfactant Triton X-100, attaining an enrichment factor close to 70. The 98 Mo/ 95 Mo measurements were characterized by RSDs from 0.5 to 1%.

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Solvent Extraction, Ion Chromatography, and Mass ...

A procedure was developed that allows precise determination of molybdenum isotope abundances in natural samples. Purification of molybdenum was first achieved by solvent extraction using di(2-ethylhexyl) phosphate. Further separation of molybdenum from isobar nuclides was obtained by ion chromatography using AG1-X8 strongly basic anion exchanger. Finally, molybdenum isotopic

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EUR-Lex - 31995L0008 - EN - EUR-Lex

Method 10.10 DETERMINATION OF MOLYBDENUM IN FERTILIZER EXTRACTS BY THE GRAVIMETRIC METHOD WITH 8-HYDROXYQUINOLINE 1. SCOPE This document describes a procedure for determining molybdenum in ferilizer extracts. 2. FIELD OF APPLICATION This procedure is applicable to extracts from samples of fertilizers obtained by Method 10.1 and 10.2 for which a ...

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Extraction and determination of molybdenum with

A differential spectrophotometric method is described for the determination of molybdenum by means of solvent extraction with tributylphosphate of the peroxymolybdate complex formed with H(2)O(2) in 3.5N H(2)SO(4). The extraction parameters are studied, and the behaviour of some other ions is reported. The method is used for ore analysis.

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Trace level determination of molybdenum in

15/01/2009  The red colored complex of molybdenum is extracted with N-phenylbenzimidoyl thiourea (PBITU) in 1-pentanol for its determination by spectrophotometry. The sensitivity of the present method is higher than other conventional thiocyanate method, due to the use of MTOAC in liquid-liquid extraction. The value of molar absorptivity of the complex with respect to molybdenum is

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(PDF) Determination of molybdenum in extracts of soil

Determination of molybdenum in extracts of soil and sewage sludge CRMs after fractionation by means of BCR modified sequential extraction procedure July 2010 Talanta 82(2):582-6

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Radiochemical Determination of Molybdenum by

Quantitative Radiochemical Determination of Molybdenum-99 by Solvent Extraction.. Analytical Chemistry 1962, 34 (6) , 625-627. DOI: 10.1021/ac60186a012. A. R. Eberle and M. W. Lerner. Determination of Tin and Molybdenum in Nuclear Reactor and Other Materials. Extraction and Spectrophotometric Determination with 8-Quinolinol..

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Methods for Determining Molybdenum - ResearchGate

A new selective and sensitive method for extraction of yellow Mo (VI)-caffeic acid complex with a liquid ion exchanger, Aliquat 336 from 4.0 pH, and spectrophotometric determination of molybdenum ...

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A colorimetric method for the determination of

Molybdenum is then separated from iron by extraction as the thiocyanate, which is then decomposed by digestion with sulphuric acid. The molybdenum is finally precipitated as the dithiol complex and extracted by amyl acetate for colorimetric estimation. The whole determination can be carried out in a Quickfit test‐tube and is both rapid and accurate.

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Determination of molybdenum in soil test extracts with ...

11/11/2008  Molybdenum concentration in the soil had a coefficient of variation (CV) of 23.5%, whereas that for the mixture was 3.95%. The low CV for the mixture indicates good precision for this method. The higher CV for the individual extracts indicates that most of the variation comes from the extraction phase of individual samples. To show the practical utility of the method, Mo maximum adsorption ...

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Quantitative Radiochemical Determination of

Differential Pulse Polarographic Determination of Trace Molybdenum in Uranium with α-Benzoinoxime Extraction. Journal of the Chinese Chemical Society 1983 , 30 (3) , 173-178.

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Determination of Tin and Molybdenum in Nuclear

01/05/2002  Flow-injection spectrophotometric determination of molybdenum(VI) by extraction with quinolin-8-ol. Analytica Chimica Acta 1993, 281 (3) , 607-610. DOI: 10.1016/0003-2670(93)85021-B. Yi-he Wu, Georg Schwedt. HPLC analysis of Cr, V and Mo using pre- in combination with on-column derivatisation by oxine, bipyridine and H2O2. Fresenius' Zeitschrift für analytische Chemie 1987, 329

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The Solvent Extraction Behavior of Inorganic Compounds ...

Extraction of molybdenum(VI) by 4-(5-nonyl)pyridine in benzene from aqueous mineral acid solutions containing thiocyanate ions. Journal of Radioanalytical and Nuclear Chemistry Articles 1984 , 82 (1) ,

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